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Abstract Young, self-luminous super-Jovian companions discovered by direct imaging provide a challenging test for planet formation and evolution theories. By spectroscopically characterizing the atmospheric compositions of these super-Jupiters, we can constrain their formation histories. Here we present studies of the recently discovered HIP 99770 b, a 16M_Juphigh-contrast companion on a 17 au orbit, using the fiber-fed high-resolution spectrograph KPIC ( $\mathcal{R}$∼ 35,000) on the Keck II telescope. OurK-band observations led to detections of H₂O and CO in the atmosphere of HIP 99770 b. We carried out free retrieval analyses usingpetitRADTRANSto measure its chemical abundances, including the metallicity and C/O ratio, projected rotation velocity ( $v\sin i$), and radial velocity (RV). We found that the companion’s atmosphere has C/O $={0.55}_{-0.04}^{+0.06}$and [M/H] $={0.26}_{-0.23}^{+0.24}$(1σconfidence intervals), values consistent with those of the Sun and with a companion formation via gravitational instability or core accretion. The projected rotation velocity $v\sin \left(i\right)<7.8$km s⁻¹is small relative to other directly imaged companions with similar masses and ages. This may imply a nearly pole-on orientation or effective magnetic braking by a circumplanetary disk. In addition, we added the companion-to-primary relative RV measurement to the orbital fitting and obtained updated constraints on orbital parameters. Detailed characterization of super-Jovian companions within 20 au like HIP 99770 b is critical for understanding the formation histories of this population. 

Abstract The ~5 Myr PDS 70 is the only known system with protoplanets residing in the cavity of the circumstellar disk from which they formed, ideal for studying exoplanet formation and evolution within its natal environment. Here, we report the first spin constraint and C/O measurement of PDS 70b from Keck/KPIC high-resolution spectroscopy. We detected CO (3.8σ) and H₂O (3.5σ) molecules in the PDS 70b atmosphere via cross correlation, with a combined CO and H₂O template detection significance of 4.2σ. Our forward-model fits, using BT-Settl model grids, provide an upper limit for the spin rate of PDS 70b (<29 km s⁻¹). The atmospheric retrievals constrain the PDS 70b C/O ratio to ${0.28}_{-0.12}^{+0.20}$(<0.63 under 95% confidence level) and a metallicity [C/H] of ${-0.2}_{-0.5}^{+0.8}$dex, consistent with that of its host star. The following scenarios can explain our measured C/O of PDS 70b in contrast with that of the gas-rich outer disk (for which C/O ≳ 1). First, the bulk composition of PDS 70b might be dominated by dust+ice aggregates rather than disk gas. Another possible explanation is that the disk became carbon enrichedafterPDS 70b was formed, as predicted in models of disk chemical evolution and as observed in both very low-mass stars and older disk systems with JWST/MIRI. Because PDS 70b continues to accrete and its chemical evolution is not yet complete, more sophisticated modeling of the planet and the disk, and higher-quality observations of PDS 70b (and possibly PDS 70c), are necessary to validate these scenarios. 

Abstract We present the projected rotational velocity and molecular abundances for HD 33632 Ab obtained via Keck Planet Imager and Characterizer (KPIC) high-resolution spectroscopy. HD 33632 Ab is a nearby benchmark brown dwarf companion at a separation of ∼20 au that straddles the L–T transition. Using a forward-modeling framework with on-axis host star spectra, which provides self-consistent substellar atmospheric and retrieval models for HD 33632 Ab, we derive a projected rotational velocity of 53 ± 3 km s⁻¹and carbon monoxide and water mass fractions of logCO = −2.3 ± 0.3 and logH₂O = −2.7 ± 0.2, respectively. The inferred carbon-to-oxygen ratio (C/O = 0.58 ± 0.14), molecular abundances, and metallicity ([C/H] = 0.0 ± 0.2 dex) of HD 33632 Ab are consistent with its host star. Although detectable methane opacities are expected in L–T transition objects, we did not recover methane in our KPIC spectra, partly due to the highvsiniand to disequilibrium chemistry at the pressures to which we are sensitive. We parameterize the spin as the ratio of rotation to the breakup velocity, and compare HD 33632 Ab to a compilation of >200 very low-mass objects (M≲ 0.1M_⊙) that have spin measurements in the literature. There appears to be no clear trend for the isolated low-mass field objects versus mass, but a tentative trend is identified for low-mass companions and directly imaged exoplanets, similar to previous findings. A larger sample of close-in gas giant exoplanets and brown dwarfs will critically examine our understanding of their formation and evolution through rotation and chemical abundance measurements. 

Abstract GQ Lup B is one of the few substellar companions with a detected cicumplanetary disk (CPD). Observations of the CPD suggest the presence of a cavity, possibly formed by an exosatellite. Using the Keck Planet Imager and Characterizer (KPIC), a high-contrast imaging suite that feeds a high-resolution spectrograph (1.9–2.5µm,R∼35,000), we present the first dedicated radial velocity (RV) observations around a high-contrast, directly imaged substellar companion, GQ Lup B, to search for exosatellites. Over 11 epochs, we find a best and median RV error of 400–1000 m s⁻¹, most likely limited by systematic fringing in the spectra due to transmissive optics within KPIC. With this RV precision, KPIC is sensitive to exomoons 0.6%–2.8% the mass of GQ Lup B (∼30M_Jup) at separations between the Roche limit and 65R_Jup, or the extent of the cavity inferred within the CPD detected around GQ Lup B. Using simulations of HISPEC, a high resolution infrared spectrograph planned to debut at W.M. Keck Observatory in 2026, we estimate future exomoon sensitivity to increase by over an order of magnitude, providing sensitivity to less massive satellites potentially formed within the CPD itself. Additionally, we run simulations to estimate the amount of material that different masses of satellites could clear in a CPD to create the observed cavity. We find satellite-to-planet mass ratios ofq> 2 × 10⁻⁴can create observable cavities and report a maximum cavity size of ∼51R_Jupcarved from a satellite. 

Abstract Using Keck Planet Imager and Characterizer high-resolution (R∼ 35,000) spectroscopy from 2.29 to 2.49μm, we present uniform atmospheric retrievals for eight young substellar companions with masses of ∼10–30M_Jup, orbital separations spanning ∼50–360 au, andT_effbetween ∼1500 and 2600 K. We find that all companions have solar C/O ratios and metallicities to within the 1σ–2σlevel, with the measurements clustered around solar composition. Stars in the same stellar associations as our systems have near-solar abundances, so these results indicate that this population of companions is consistent with formation via direct gravitational collapse. Alternatively, core accretion outside the CO snowline would be compatible with our measurements, though the high mass ratios of most systems would require rapid core assembly and gas accretion in massive disks. On a population level, our findings can be contrasted with abundance measurements for directly imaged planets withm< 10M_Jup, which show tentative atmospheric metal enrichment compared to their host stars. In addition, the atmospheric compositions of our sample of companions are distinct from those of hot Jupiters, which most likely form via core accretion. For two companions withT_eff∼ 1700–2000 K (κAnd b and GSC 6214–210 b), our best-fit models prefer a nongray cloud model with >3σsignificance. The cloudy models yield 2σ−3σlowerT_efffor these companions, though the C/O and [C/H] still agree between cloudy and clear models at the 1σlevel. Finally, we constrain¹²CO/¹³CO for three companions with the highest signal-to-noise ratio data (GQ Lup b, HIP 79098b, and DH Tau b) and report $v\sin i$and radial velocities for all companions. 

Abstract Vortex fiber nulling (VFN) is a technique for detecting and characterizing faint companions at small separations from their host star. A near-infrared (∼2.3μm) VFN demonstrator mode was deployed on the Keck Planet Imager and Characterizer (KPIC) instrument at the Keck Observatory and presented earlier. In this Letter, we present the first VFN companion detections. Three targets, HIP 21543 Ab, HIP 94666 Ab, and HIP 50319 B, were detected with host–companion flux ratios between 70 and 430 at and within one diffraction beamwidth (λ/D). We complement the spectra from KPIC VFN with flux ratio and position measurements from the CHARA Array to validate the VFN results and provide a more complete characterization of the targets. This Letter reports the first direct detection of these three M dwarf companions, yielding their first spectra and flux ratios. Our observations provide measurements of bulk properties such as effective temperatures, radial velocities, and $v\sin i$, and verify the accuracy of the published orbits. These detections corroborate earlier predictions of the KPIC VFN performance, demonstrating that the instrument mode is ready for science observations. 

Abstract Direct imaging studies have mainly used low-resolution spectroscopy ( R ∼ 20–100) to study the atmospheres of giant exoplanets and brown dwarf companions, but the presence of clouds has often led to degeneracies in the retrieved atmospheric abundances (e.g., carbon-to-oxygen ratio, metallicity). This precludes clear insights into the formation mechanisms of these companions. The Keck Planet Imager and Characterizer (KPIC) uses adaptive optics and single-mode fibers to transport light into NIRSPEC ( R ∼ 35,000 in the K band), and aims to address these challenges with high-resolution spectroscopy. Using an atmospheric retrieval framework based on petitRADTRANS , we analyze the KPIC high-resolution spectrum (2.29–2.49 μ m) and the archival low-resolution spectrum (1–2.2 μ m) of the benchmark brown dwarf HD 4747 B ( m = 67.2 ± 1.8 M Jup , a = 10.0 ± 0.2 au, T eff ≈ 1400 K). We find that our measured C/O and metallicity for the companion from the KPIC high-resolution spectrum agree with those of its host star within 1 σ –2 σ . The retrieved parameters from the K -band high-resolution spectrum are also independent of our choice of cloud model. In contrast, the retrieved parameters from the low-resolution spectrum are highly sensitive to our chosen cloud model. Finally, we detect CO, H 2 O, and CH 4 (volume-mixing ratio of log(CH 4 ) = −4.82 ± 0.23) in this L/T transition companion with the KPIC data. The relative molecular abundances allow us to constrain the degree of chemical disequilibrium in the atmosphere of HD 4747 B, and infer a vertical diffusion coefficient that is at the upper limit predicted from mixing length theory. 

Abstract M dwarfs are common host stars to exoplanets but often lack atmospheric abundance measurements. Late-M dwarfs are also good analogs to the youngest substellar companions, which share similarT_eff∼ 2300–2800 K. We present atmospheric analyses for the M7.5 companion HIP 55507 B and its K6V primary star with Keck/KPIC high-resolution (R∼ 35,000)K-band spectroscopy. First, by including KPIC relative radial velocities between the primary and secondary in the orbit fit, we improve the dynamical mass precision by 60% and find $M_B={88.0}_{-3.2}^{+3.4}{M}_{\mathrm{Jup}}$, putting HIP 55507 B above the stellar–substellar boundary. We also find that HIP 55507 B orbits its K6V primary star with $a={38}_{-3}^{+4}$au ande= 0.40 ± 0.04. From atmospheric retrievals of HIP 55507 B, we measure [C/H] = 0.24 ± 0.13, [O/H] = 0.15 ± 0.13, and C/O = 0.67 ± 0.04. Moreover, we strongly detect¹³CO (7.8σsignificance) and tentatively detect ${\mathrm{H}}_2^{18}\mathrm{O}$(3.7σsignificance) in the companion’s atmosphere and measure ${}^{12}\mathrm{CO}{/}^{13}\mathrm{CO}={98}_{-22}^{+28}$and ${\mathrm{H}}_2^{16}\mathrm{O}/{\mathrm{H}}_2^{18}\mathrm{O}={240}_{-80}^{+145}$after accounting for systematic errors. From a simplified retrieval analysis of HIP 55507 A, we measure ${}^{12}\mathrm{CO}{/}^{13}\mathrm{CO}={79}_{-16}^{+21}$and ${\mathrm{C}}^{16}\mathrm{O}/{\mathrm{C}}^{18}\mathrm{O}={288}_{-70}^{+125}$for the primary star. These results demonstrate that HIP 55507 A and B have consistent¹²C/¹³C and¹⁶O/¹⁸O to the <1σlevel, as expected for a chemically homogeneous binary system. Given the similar flux ratios and separations between HIP 55507 AB and systems with young substellar companions, our results open the door to systematically measuring¹³CO and ${\mathrm{H}}_2^{18}\mathrm{O}$abundances in the atmospheres of substellar or even planetary-mass companions with similar spectral types.